2,5-Dimethoxybenzaldehyde thiosemicarbazone
نویسندگان
چکیده
منابع مشابه
Synthesis and crystal structure of Zinc (II) Complex [Zn(25-MBTSC)2I2]
Zinc (II) complex, [Zn(25-MBTSC)2I2] (1), where (25-MBTSC = (E)-2-(2,5-dimethoxybenzaldehyde) thiosemicarbazone, has been synthesized from the reaction of ZnI2 with 25-MBTSC in methanol as solvent at 25 ºC. It was characterized by elemental analysis (CHN) and is confirmed by single-crystal X-ray diffraction analysis. The complex 1 crystallizes in a triclinic system, with space group P-ī, having...
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In this study, 2-formylpyridine thiosemicarbazones and three different heterocyclic pharmacophores were combined to prepare thiosemicarbazone–piperazine mPip-FTSC (HL1) and mPip-dm-FTSC (HL2), thiosemicarbazone–morpholine Morph-FTSC (HL3) and Morph-dm-FTSC (HL4), thiosemicarbazone–methylpyrrole-2-carboxylate hybrids mPyrr-FTSC (HL5) and mPyrr-dm-FTSC (HL6) as well as their copper(II) complexes ...
متن کاملAurophilicity in gold(I) thiosemicarbazone clusters.
The reaction of the phosphine thiosemicarbazone ligands HLPH and HLPMe with Au(I) ions yields the gold complexes [Au(3)(HLPH)(2)Cl(2)]Cl·2MeOH (1·2MeOH) and [Au(2)(HLPMe)Cl(2)] (2). The structures determined by X Ray diffraction, [Au(3)(HLPH)(2)Cl(2)]Cl·4MeOH (1·4MeOH) and [Au(2)(HLPMe)Cl(2)](2) (2), are the first examples of gold(I) thiosemicarbazone clusters showing aurophilicity. The structu...
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Only a few drugs are available for treating sleeping sickness and nagana disease; parasitic infections caused by protozoans of the genus Trypanosoma in sub-Saharan Africa. There is an urgent need for the development of new medicines for chemotherapy of these devastating diseases. In this study, three newly designed thiosemicarbazone iron chelators, TSC24, Dp44mT and 3-AP, were tested for in vit...
متن کاملStable gold(III) complexes with thiosemicarbazone derivatives.
Novel thiosemicarbazonato complexes of gold(III) have been prepared from reactions of [Au(damp-C1,N)Cl2(damp- = 2-(N,N-dimethylaminomethyl)phenyl) or [NBu4][AuCl4] with 2-pyridineformamide thiosemicarbazones (HL). The thiosemicarbazones deprotonate and coordinate as mononegative, tridentate NNS ligands to gold to give [Au(Hdamp-C1)(L)]Cl2 or [AuCl(L)]Cl complexes. The organometallic damp- ligan...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808035198